Temporal and Spatial Changes in pH Values and Phosphate Phosphorus Concentrations in the Bocegaj Watercourse and Their Impact on Fish Life

Authors

  • Mária Babošová Slovak University of Agriculture in Nitra, Faculty of Agrobiology and Food Resources, Institute of Plant and Environmental Sciences, Slovak Republic
  • Jana Ivanič-Porhajášová Slovak University of Agriculture in Nitra, Faculty of Agrobiology and Food Resources, Institute of Plant and Environmental Sciences, Slovak Republic

Keywords:

brook, government regulation, pH, phosphates phosphorus, pond

Abstract

Between 2022 and 2024, they were monitored in the Bocegaj watercourse, where pH and phosphate phosphorus (P-PO43-) concentrations were measured. During the period under review, pH values were relatively stable, and the average value reached 7.69. Seasonal changes indicated higher pH values in winter and summer, which may have been caused by reduced biological activity in winter and increased photosynthetic activity of aquatic organisms in summer. Spatial analysis showed that the most stable pH values were recorded below the pond outflow into the stream, while the most pronounced increase occurred in the northwestern part of the pond. The average concentration of phosphate phosphorus for the entire period under study was 0.52 mg·dm-3. The highest concentration was recorded in June and the lowest in April. Spatial differences indicated a substantial increase in phosphate phosphorus concentrations at the sampling site located below the wastewater treatment plant outflow. According to the Regulation of the Government of the Slovak Republic No. 269/2010 Coll., the water in the Bocegaj watercourse and in the Kolíňany pond meets the criteria for the breeding and life of cyprinid fish in terms of pH but does not meet these requirements in terms of phosphate phosphorus concentrations.

References

Adamec, M. et al. (2016). Current problems and damages in fisheries (1st ed.). Slovak Fishermen‘s Association.

Antalová, M. (2022). Selected chemical characteristics in the surface water of the Nitra River and the Small Nitra dead branch. Science. https://www.preveda.sk/en/abstrakt/vybrane-chemicke-charakteristiky-v-povrchovej-vode-rieky-nitra-mrtveho-ramena-mala-nitra

Armah, F. et al. (2020). Relationship of Trace Metal Covariates and pH Distribution in Groundwater within Gold mining and non-gold mining Areas in Ghana. Preprints, 120321. https://doi.org/10.20944/preprints202012.0321.v1

Biedunkova, O. et al. (2025). A study of surface water quality using organic pollution indices: Comparative characteristics and educational opportunities. Water Quality Research Journal, 60(2), 333–347. https://doi.org/10.2166/wqrj.2025.044

Boyd, C.E. (2015). Water Quality (2nd ed.). Springer. https://doi.org/10.1007/978-3-319-17446-4_12

Fondriest Environmental. (2013, November 19). pH of water. Fundamentals of Environmental Measurements. https://www.fondriest.com/environmental-measurements/parameters/water-quality/ph/

Hejzlar, J., Znachor, P., Sobolíková, Z., & Rohlík, V. (2015). Vysoká eutrofizační účinnost fosforu původem z odpadních vod v nádrži Lipno [High eutrophication efficiency of phosphorus originating from wastewater in the Lipno reservoir]. In D. Kosour et al. (Eds.), Sborník konference Vodní nádrže 2015 (pp. 81–87). Povodí Moravy.

Hickin, E.J. (1995). River Geomorphology. Wiley Press.

Hu, Y. et al. (2019). Logistics network management of livestock waste for spatiotemporal control of nutrient pollution in water bodies. ACS Sustainable Chemistry & Engineering, 7(22), 18359–18374. https://doi.org/10.1021/acssuschemeng.9b03920

Humpl, M., & Pivnička, K. (2006). Fish assemblages as influenced by environmental factors in streams in protected areas of the Czech Republic. Ecology of Freshwater Fish, 15, 96–103. https://doi.org/10.1111/j.1600-0633.2006.00126.x

Immerová, B. (2012). Water world under magnifying glass (1st ed.). Daphne Bratislava.

Kiemle, L., & Fuchs, Š. (2022). Dissolved Phosphorus Concentrations in Surface Runoff from Agricultural Land Based on Calcium – Acetate – Lactate Soluble Phosphorus Soil Contents. Water, 14(11), 1742. https://doi.org/10.3390/w14111742

Onojake, M.C. et al. (2011). A Statistical Approach for Evaluation of the Effects of Industrial and Municipal Wastes on Warri Rivers, Niger Delta, Nigeria. Water Quality Exposure and Health, 3(2), 91–99. https://doi.org/10.1007/s12403-11-0046-7

Perlman, H. (2014). Sediment and Suspended Sediment. In The USGS Water Science School. http://water.usgs.gov/edu/sediment.html

Policar, T. et al. (2018). Operational manual for the effective operation of intensive aquaculture using races. University of South Bohemia in České Budějovice.

Regulation of the Government of the SR no. 269/2010 Coll., which sets requirements for achieving good water status [Nariadenie vlády SR č. 269/2010 Z. z., ktorým sa ustanovujú požiadavky na dosiahnutie dobrého stavu vôd]. (2010). ASPI. https://www.aspi.sk/products/lawText/1/71240/1/2/nariadenie-c-269-2010-zz-ktorym-sa-ustanovuju-poziadavky-na-dosiahnutie-dobreho-stavu-vod/nariadenie-c-269-2010-zz-ktorym-sa-ustanovuju-poziadavky-na-dosiahnutie-dobreho-stavu-vod

Saalidong, B.M. et al. (2022). Examining the dynamics of the relationship between water pH and other water quality parameters in ground and surface water systems. PLoS One, 17(1), e0262117. https://doi.org/10.1371/journal.pone.0262117

Sabová, Z. (2020). Evaluation of surface water quality in the vicinity of the small Ratka reservoir. In Collection of young experts‘ competition papers 2020. Slovak Hydrometeorological Institute.

Singh, K.P. et al. (2005). Water quality assessment and apportionment of pollution sources of Gomti river (India) using multivariate statistical techniques – a case study. Analytica Chimica Acta, 538(1–2), 355–374. https://doi.org/10.1016/j.aca.2005.02.006

Weiner, E. R. (2008). Applications of environmental aquatic chemistry: A practical guide (2nd ed.). CRC Press. https://doi.org/10.1201/9781420008371

Wojciechowska, E. et al. (2019). Seasonal changes of the concentrations of mineral forms of nitrogen and phosphorus in watercourses in the agricultural catchment area (Bay of Puck, Baltic Sea, Poland). Water Supply, 19(3), 986. https://doi.org/10.2166/ws.2018.190

Zhang, H. et al. (2023). Exploration of the factors that influence total phosphorus in surface water and an evaluation of surface water vulnerability based on an advanced algorithm and traditional index method. Journal of Environmental Management, 342(15), 118155. https://doi.org/10.1016/j.jenvman.2023.118155

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Published

2026-10-01

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Section

Animal Science